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The University of Insubria CV
The University of Insubria CV
The University of Insubria CV The University of Insubria CV Stefano Tollari
The University of Insubria CV
 

Contact data

Associate Professor
Department of Chemical and Environmental Sciences
Via Valleggio 11, I-22100 Como
Tel: +390312386471
Fax: +390312386449
E-mail: stefano.tollari@uninsubria.it
 

Biography

 Stefano Tollari was born in Lama Mocogno, Italy in 1949. He received his Laurea degree in Chemistry in 1974 (University of Milano). During the period 1976-1983 he carried out his research in the group of Professor Danieli at the same University and supported Organic Chemistry classes as a tutor. In 1980 he got a permanent position as a Researcher in Organic Chemistry at the School of Sciences of University of Milan. He continued his research activity in collaboration with Professor Rindone for the period 1983-1989 and with Professor Cenini (Organometallic Chemistry) for the period 1989-1998. In 1999 he was appointed Associate Professor at the University of Insubria in Como, School of Sciences.
 

Research interests

Stefano Tollari’s research interests mainly deal with the following topics:

a) structural, synthetic and spectroscopic investigations of organometallic compounds

b) metal catalysed formation of C-C bond

c) synthesis of new ligands for the organometallic catalysis. He is author and co-author of 86 papers on international journals and about 35 communications in National and International Meetings.

National collaborations:
Prof.G.Palmisano, University of Insubria
Prof. G.Cravotto, University of Torino
Dr.A.Penoni, University of Insubria

 

Teaching experience and appointments

 Current academic courses:
General and Inorganic Chemistry
Basic Principles of Organometallic Chemistry
 

Representative  publications

 S.Cenini, S.Tollari, A.Penoni e C.Cereda
CATALYTIC AMINATION OF UNSATURATED HYDRO-CARBONS: REACTIONS OF p-NITROPHENYLAZIDE WITH ALKENES CATALYSED BY METALLO-PORPHYRINS
J. Mol. Cat. A: Chem, 1999, 137 135-146

F.Ragaini, S.Cenini, S.Tollari, G.Tummolillo e R.Beltrami
ALLYLYC AMINATION OF UNACTIVATED OLEFINS BY NITROARENES CATALYSED BY RUTHENUIM COM-PLEXES. A REACTION INVOLVING AN INTERMO-LECULAR C-H ACTIVATION
Organometallics, 1999 18 928-942

S.Cenini, G. Cravotto, G.B. Giovenzana, G . Palmisano e S.Tollari
POLYOXYGENATED COUMARINS. OXONIUM YLIDES en route TO POLYOXA-MACROCYCLIC COUMARINS
Tetrahedron, 1999 55 6577-6584

S. Tollari, A. Penoni, S. Cenini
"THE UNPRECEDENTED DETECTION OF THE INTERMEDIATE OF N-HYDROXY DERIVATIVES DURING THE. CARBONYLATION OF 2'-NITROCHALCONES AND 2-NITROSTYRENES CATALYSED BY PALLADIUM. "
J. Mol. Catal. : A Chemical 2000, 152, 47.

A. Maldotti, L. Andreotti, A. Molinari, S. Tollari, A. Penoni, S. Cenini
"PHOTOCHEMICAL AND PHOTOCATALYTIC REDUCTION OF NITROBENZENE IN THE PRESENCE OF CYCLO-HEXENE. "
J. Photochem. Photobiol. A: Chemical 2000, 133, 129

S. Cenini, G. Cravotto, G. B. Giovenzana, A. Penoni, S. Tollari, G. Palmisano
"RHODIUM (II) CATALYSED DECOMPOSITION OF 3-DIAZO-4-HYDROXYCOUMARIN. AN EASY ACCESS TO FUROCOUMARIN RING SYSTEM."
J. Mol. Catal. : A Chemical 164 2000 165

S. Tollari, S. Cenini, A. Penoni, G. Granata, G. Palmisano, F. Demartin "CARBENE COMPLEXES OF CYCLOPLATINATED 1-H-INDOLE-1-METHYIL-2-(2'-PYRIDINE). THE CRYSTAL AND MOLECULAR STRUCTURE OF s-íPT[1H-INDOLE-1-METHYL-2-(2'-PYRIDINIL-C3, N'](DMSO)CLý AND OF s-íPT[1H-INDOLE-1-METHYL-2-(2'-PYRIDINIL-C3,N']-[=C(OCH2CH3) (CH2C6H5)]CLý"
J. Organomet. Chem.  2000 608 (1-2) 34

S. Cenini, E. Gallo, A. Penoni, F. Ragaini, S. Tollari
"CATALYTIC AMINATION OF SATURATED C-H BONDS BY ORGANIC AZIDES. A NEW REACTION LEADING TO SECONDARY AMINES AND SCHIFF BASES."
Chem. Commun. 2000 2265

S. Cenini, G. Cravotto, G. B. Giovenzana, A. Penoni, S. Tollari, G. Palmisano
SYNTHESIS OF FUROCOUMARINS VIA RHODIUM (II)-CATALYSED HETEROCYCLISATION OF 3-DIAZOBENZO-PYRAN-2,4(3H)-DIONE WITH TERMINAL ALKYNES
Synthesis 2001 5 735

A.Penoni, R. Wanke, S.Tollari.
CYCLOPROPANATION OF OLEFINS WITH DIAZOALKA-NES, CATALYZED BY CO-II(PORPHYRIN) COMPLEXES - A SYNTHETIC AND MECHANISTIC INVESTIGATION AND THE MOLECULAR STRUCTURE OF CO-III(TPP)-(CH2CO2ET) (TPP = DIANION OF MESO-TETRAPHENYL-PORPHYRIN)
European Journal of Inorganic Chemistry (7): 2003 1452

F. Ragaini, A. Penoni E. Gallo
AMINATION OF BENZYLIC C-H BONDS BY ARYLAZIDES CA-TALYZED BY CO-II-PORPHYRIN COMPLEXES: A SYNTHETIC AND MECHANISTIC STUDY
Chemistry-A European Journal 9 (1): 2003 249

S. Cenini, G. Cravotto, GB.Giovenzana.
DIRUTHENIUM(II,II) TETRAKIS(ACETATE) AS A CATALYST OF CHOICE FOR INTERMOLECULAR INSERTION OF STABILIZED DIAZOCOMPOUNDS INTO O-H BONDS
Tetrahedron Letters 43 (20): 2002 3637

G.Cravotto, F. Demartin, G.Palmisano S.Tollari
NOVEL CYCLOMETALLATED PD(II) AND PT(II) COMPLEXES WITH INDOLE DERIVATIVES AND THEIR USE AS CATALYSTS IN HECK REACTION
Journal of Organometallic Cemistry 690 (8): 2005 2017

L. Goldoni, G. Cravotto, A. Penoni, S.Tollari
THE RHODIUM CARBENOID ROUTE TO 3-ARYL-4-HYDROXYCOUMARINS: SYNTHESIS OF DERRUSNIN
Synletters (6): 2005 927

A.Maldotti, R. Amadelli, L.Samiolo, S.Tollari, A. Penoni
PHOTOCATALYTIC FORMATION OF A CARBAMATE THRO-UGH ETHANOL-ASSISTED CARBONYLATION OF P-NITRO-TOLUENE
Chemical Communications (13): 20051749

G. Cravotto M. Beggiato, A. Penoni, S.Tollari G. Palmisano,
HIGH-INTENSITY ULTRASOUND AND MICROWAVE, ALONE OR COMBINED, PROMOTE PD/C-CATALYZED ARYL-ARYL COUPLINGS
Tetrahedron Letters 46 (13): 2005 2267

G. Cravotto, G. Palmisano, S. Tollari, A. Penoni
THE SUZUKI HOMOCOUPLING REACTION UNDER HIGH-INTENSITY ULTRASOUND
Ultrasonics Sonochemistry12 (1-2): 2005 91

 
 
   
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